The Speedmaster Professional 3592.50 was produced from the late 1980’s or early 1990’s and has a hesalite crystal and sapphire case back with both a tritium dial and handset.
These were produced until ~1997 when they changed the reference to 3572.50 (along with some aesthetic changes to the movement; meaning non-mechanical changes) - some of the early versions of that reference also had tritium dials and handsets up until 1998 (or so) with the change to luminova.
Don’t have my copy of Moon Watch Only handy to confirm production dates and/or additional references that had that combination. There are other references that were LE or numbered editions (Apollo 11’s) that had tritium and sapphire as well.
There is a lot more detail to what I shared above, but those are two references you can start to check out and I’m sure others here have plenty more to share
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