As a seller, I've had bad luck with PayPal and I don't accept it for large amounts. Not even if the buyer pays the fees. Long story.
If you have a good feeling about the seller, which you seem to, then you're probably OK. I like to google them, sometimes I'll ask for a copy of their driver's license. You can then get a real address, see if it's a house or apartment. If it's the former, then you can verify that they own it, in which case you've got a pretty good chance of finding them if something were to go wrong.
A legitimate seller shouldn't have a problem sending you all of their contact information and providing you with enough information to vet them thoroughly.
I've never used escrow.com but that sounds like an excellent idea as well.
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