Did you completely remove the setting lever (detent) screw? If so, you've probably dislodged part of the keyless works and now the stem is caught. You only need to unscrew that screw one and a half turns and then lightly press it to remove the stem.
It's unlikely to be rusted into the case if you can wind the watch but any way forward depends on your watch and I wouldn't want to say how I'd do it without the watch in hand. I wouldn't try to cut the stem or remove the calibre from the front as they'll both be dead ends. I'd prefer to go in from the back of the watch to try and resolve the issue that is stopping the stem removal. I sometimes get watches in that the owner has accidentally damaged through trying to do something themselves but, that's up to them. If you want to make some adjustments yourself, you'll find it quickly becomes very difficult but it can make life interesting
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Regards, Chris
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