AFAIK the markers are not gold plated but solid gold, also the hands should be (when they left the factory) however the winding crown and buckle were only gold plated... even on the 18K cased models.
Tarnishing of gold is not uncommon, even on outer case parts - when they sat in a vault or drawer for quite some time.
I can not tell you what happened chemically, I can only confirm that it is not uncommon and the markers and hands can be polished to shine again (if you want to erase the patina which took decades to build up).
I saw tarnishing of gold markers even on a vintage Patek pocket watch and you can assume that these markers had been executed in 18K sold gold as you can expect from PP. I think it is not a bad alloy, it just happens under certain (unknown) circumstances - I assume that moisture content of the air is one possible factor.
Hope this helps
erich
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